Browsing by Author "Gulgun, M. A."

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A comparative evaluation of sepiolite and nano-montmorillonite on the rheology of cementitious materials for 3D printing
(Elsevier, 2022-10-03) Aydın, Eylül Mina; Kara, Ahmet Burhan; Bundur, Zeynep Başaran; Özyurt, N.; Bebek, Özkan; Gulgun, M. A.; Civil Engineering; Mechanical Engineering; BUNDUR, Zeynep Başaran; BEBEK, Özkan; Aydın, Eylül Mina; Kara, Ahmet Burhan
Through the last decade, methods of digital manufacturing of concrete gained a significant interest compared to conventional concrete. The main challenge in additive manufacturing (3D printing) is to design a highly thixotropic cementitious system. This study aims to investigate the use of sepiolite as a rheology modifier as a novel approach to improve the thixotropic behavior and adapt cementitious systems to 3D printing. To understand the influence of sepiolite on rheological properties, a comparative evaluation with nano-montmorillonite was established. The effectiveness of clay addition was also investigated in fly-ash amended cement-based materials. The rheological analysis was done on cement-paste samples containing both clays in terms of their effects on thixotropy, structural build-up, and recovery. A preliminary printability assessment was done with a lab scale printer having a ram extruder. The results show that the incorporation of clays increased the dynamic yield stress and time-dependent evolution of static yield stress. Moreover, the addition of clays improved the thixotropic behavior of cement-based systems, particularly those containing fly-ash. Herein, the sepiolite was found to be more effective compared to nano-montmorillonite in terms of improving thixotropy, structural build-up and recovery. The results showed that use of fly-ash enhances the printability of the mix for the specified extruder and the samples containing 1% nano-montmorillonite or 0.5% sepiolite can be printed. The positive effects of sepiolite were attributed to opposing surface charges of the clay layers and its micro-fibrous microstructure. The findings in this study enabled an in-depth understanding of the rheology and printability of fly-ash amended clay containing printable cement-based mortars.
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End-of-life materials used as supplementary cementitious materials in the concrete industry
(MDPI, 2020-04) Nicoara, A. I.; Stoica, A. E.; Vrabec, M.; Rogan, N. S.; Sturm, S.; Ow-Yang, C.; Gulgun, M. A.; Bundur, Zeynep Başaran; Ciuca, I.; Vasile, B. S.; Civil Engineering; BUNDUR, Zeynep Başaran
A sustainable solution for the global construction industry can be partial substitution of Ordinary Portland Cement (OPC) by use of supplementary cementitious materials (SCMs) sourced from industrial end-of-life (EOL) products that contain calcareous, siliceous and aluminous materials. Candidate EOL materials include fly ash (FA), silica fume (SF), natural pozzolanic materials like sugarcane bagasse ash (SBA), palm oil fuel ash (POFA), rice husk ash (RHA), mine tailings, marble dust, construction and demolition debris (CDD). Studies have revealed these materials to be cementitious and/or pozzolanic in nature. Their use as SCMs would decrease the amount of cement used in the production of concrete, decreasing carbon emissions associated with cement production. In addition to cement substitution, EOL products as SCMs have also served as coarse and also fine aggregates in the production of eco-friendly concretes.
Open Access
Fly-ash evaluation as potential EOL material replacement of cement in pastes: Morpho-structural and physico-chemical properties assessment
(MDPI, 2022-04-24) Vasile, B. S.; Nicoara, A. I.; Surdu, V. A.; Ene, V. L.; Neacsu, I. A.; Stoica, A. E.; Oprea, O.; Boierasu, I.; Trusca, R.; Vrabec, M.; Miklavic, B.; Sturm, S.; Ow-Yang, C.; Gulgun, M. A.; Bundur, Zeynep Başaran; Civil Engineering; BUNDUR, Zeynep Başaran
The main objective of the study was to produce alternative binder materials, obtained with low cost, low energy consumption, and low CO2 production, by regenerating end-of-life (EOL) materials from mineral deposits, to replace ordinary Portland cement (OPC). The materials analyzed were ash and slag from the Turceni thermal power plant deposit, Romania. These were initially examined for morphology, mineralogical composition, elemental composition, degree of crystallinity, and heating behavior, to determine their ability to be used as a potential source of supplementary cementitious materials (SCM) and to establish the activation and transformation temperature in the SCM. The in-situ pozzolanic behavior of commercial cement, as well as cement mixtures with different percentages of ash addition, were further observed. The mechanical resistance, water absorption, sorptivity capacity, resistance to alkali reactions (ASR), corrosion resistance, and resistance to reaction with sulfates were evaluated in this study using low-vacuum scanning electron microscopy.