Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene
dc.contributor.author | Yaman, P. K. | |
dc.contributor.author | Erer, H. | |
dc.contributor.author | Arici, M. | |
dc.contributor.author | Fındıkçı, İlknur Eruçar | |
dc.contributor.author | Yesilel, O. Z. | |
dc.date.accessioned | 2020-08-12T11:31:01Z | |
dc.date.available | 2020-08-12T11:31:01Z | |
dc.date.issued | 2019-03-24 | |
dc.identifier.issn | 0020-1693 | en_US |
dc.identifier.uri | http://hdl.handle.net/10679/6765 | |
dc.identifier.uri | https://www.sciencedirect.com/science/article/abs/pii/S0020169318316451 | |
dc.description.abstract | The hydrothermal reactions of some metal ions with 2,2'-dimethylglutaric acid (22dmgH(2)) and 1,2-bis(imidazol-1-ylmethyl)benzene (obix) newly afford four coordination polymers are called, {[Co-2 (mu-22dmg)(2)(mu-obix)(2)]center dot 1.5H(2)O}(n) (1), {[Cu(mu-22dmg)(mu-obix)]center dot H2O}(n) (2), {[Zn-2(mu-22dmg)(2)(mu-obix)(2)]center dot 2H(2)O}(n) (3) and [Cd-2(mu-22dmg)(2)(mu-obix)(2)(H2O)](n) (4). All of the complexes were characterized by elemental analysis, IR spectra, single crystal X- ray diffraction, powder X-ray diffraction (PXRD), and thermal analysis techniques. Furthermore, photoluminescence and topological properties were studied. The X-ray single crystal study shows that complexes 1, 3 and 4 display 3-fold parallel interpenetrating networks with hcb topology showing an unusual 2D + 2D + 2D -> 2D structures. Topological analysis reveals that complex 2 has an uninodal 4-c net sql topology with the point symbol of 4(4).6(2). Atomically-detailed simulations were finally performed to compute hydrogen (H-2) uptake in these complexes at 77 K. | en_US |
dc.description.sponsorship | BIDEP Tubitak-2218 post-doctoral research scholarship ; Turkish Academy of Sciences | |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | |
dc.rights | restrictedAccess | |
dc.title | Hydrothermal synthesis and characterization of two dimensional coordination polymers with 2,2′-dimethylglutarate and 1,2-bis(imidazol-1-ylmethyl)benzene | en_US |
dc.type | Article | en_US |
dc.peerreviewed | yes | en_US |
dc.publicationstatus | Published | en_US |
dc.contributor.department | Özyeğin University | |
dc.contributor.authorID | (ORCID 0000-0002-6059-6067 & YÖK ID 260094) Eruçar, İlknur | |
dc.contributor.ozuauthor | Fındıkçı, İlknur Eruçar | |
dc.identifier.volume | 488 | en_US |
dc.identifier.startpage | 229 | en_US |
dc.identifier.endpage | 237 | en_US |
dc.identifier.wos | WOS:000458696800027 | |
dc.identifier.doi | 10.1016/j.ica.2018.12.039 | en_US |
dc.subject.keywords | Coordination polymers | en_US |
dc.subject.keywords | Hydrothermal synthesis method | en_US |
dc.subject.keywords | 2,2′-Dimethylglutarate complex | en_US |
dc.subject.keywords | 1,2-Bis(imidazol-1-ylmethyl)benzene | en_US |
dc.identifier.scopus | SCOPUS:2-s2.0-85060511232 | |
dc.contributor.authorFemale | 1 | |
dc.relation.publicationcategory | Article - International Refereed Journal - Institution Academic Staff |
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