Metal-organic framework glasses with permanent accessible porosity
dc.contributor.author | Zhou, C. | |
dc.contributor.author | Longley, L. | |
dc.contributor.author | Krajnc, A. | |
dc.contributor.author | Smales, G. J. | |
dc.contributor.author | Qiao, A. | |
dc.contributor.author | Fındıkçı, İlknur Eruçar | |
dc.contributor.author | Doherty, C. M. | |
dc.contributor.author | Thornton, A. W. | |
dc.contributor.author | Hill, A. J. | |
dc.contributor.author | Ashling, C. W. | |
dc.contributor.author | Qazvini, O. T. | |
dc.contributor.author | Lee, S. J. | |
dc.contributor.author | Chater, P. A. | |
dc.contributor.author | Terrill, N. J. | |
dc.contributor.author | Smith, A. J. | |
dc.contributor.author | Yue, Y. | |
dc.contributor.author | Mali, G. | |
dc.contributor.author | Keen, D. A. | |
dc.contributor.author | Telfer, S. G. | |
dc.contributor.author | Bennett, T. D. | |
dc.date.accessioned | 2019-02-05T13:21:49Z | |
dc.date.available | 2019-02-05T13:21:49Z | |
dc.date.issued | 2018-11-28 | |
dc.identifier.issn | 2041-1723 | en_US |
dc.identifier.uri | http://hdl.handle.net/10679/6148 | |
dc.identifier.uri | https://www.nature.com/articles/s41467-018-07532-z | |
dc.description.abstract | To date, only several microporous, and even fewer nanoporous, glasses have been produced, always via post synthesis acid treatment of phase separated dense materials, e.g. Vycor glass. In contrast, high internal surface areas are readily achieved in crystalline materials, such as metal-organic frameworks (MOFs). It has recently been discovered that a new family of melt quenched glasses can be produced from MOFs, though they have thus far lacked the accessible and intrinsic porosity of their crystalline precursors. Here, we report the first glasses that are permanently and reversibly porous toward incoming gases, without post-synthetic treatment. We characterize the structure of these glasses using a range of experimental techniques, and demonstrate pores in the range of 4 – 8 Å. The discovery of MOF glasses with permanent accessible porosity reveals a new category of porous glass materials that are elevated beyond conventional inorganic and organic porous glasses by their diversity and tunability. | en_US |
dc.description.sponsorship | Royal Society ; China Scholarship Council ; Elite Research Travel Scholarship from the Danish Ministry of Higher Education and Science ; Slovenian Research Agency ; Australian Research Council ; Veski Inspiring Women Fellowship ; EPSRC ; Commonwealth Scientific and Industrial Research Organization (CSIRO) ; RSNZ Marsden Fund grant | |
dc.language.iso | eng | en_US |
dc.publisher | Nature Publishing Group | en_US |
dc.relation.ispartof | Nature Communications | |
dc.rights | openAccess | |
dc.title | Metal-organic framework glasses with permanent accessible porosity | en_US |
dc.type | Article | en_US |
dc.description.version | Publisher version | en_US |
dc.peerreviewed | yes | en_US |
dc.publicationstatus | Published | en_US |
dc.contributor.department | Özyeğin University | |
dc.contributor.authorID | (ORCID 0000-0002-6059-6067 & YÖK ID 260094) Eruçar, İlknur | |
dc.contributor.ozuauthor | Fındıkçı, İlknur Eruçar | |
dc.identifier.volume | 9 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.startpage | 1 | en_US |
dc.identifier.endpage | 9 | en_US |
dc.identifier.wos | WOS:000451433800012 | |
dc.identifier.doi | 10.1038/s41467-018-07532-z | en_US |
dc.identifier.scopus | SCOPUS:2-s2.0-85057550866 | |
dc.contributor.authorFemale | 1 | |
dc.relation.publicationcategory | Article - International Refereed Journal - Institutional Academic Staff |
Files in this item
This item appears in the following Collection(s)
Share this page