Flux melting of metal–organic frameworks
dc.contributor.author | Longley, L. | |
dc.contributor.author | Collins, S. M. | |
dc.contributor.author | Li, S. C. | |
dc.contributor.author | Smales, G. L. | |
dc.contributor.author | Fındıkçı, İlknur Eruçar | |
dc.contributor.author | Qiao, A. | |
dc.contributor.author | Hou, J. | |
dc.contributor.author | Doherty, C. M. | |
dc.contributor.author | Thornton, A. W. | |
dc.contributor.author | Hill, A. J. | |
dc.contributor.author | Yu, X. | |
dc.contributor.author | Terrill, N. J. | |
dc.contributor.author | Smith, A. J. | |
dc.contributor.author | Cohen, S. M. | |
dc.contributor.author | Midgley, P. A. | |
dc.contributor.author | Keen, D. A. | |
dc.contributor.author | Telfer, S. G. | |
dc.contributor.author | Bennett, T. D. | |
dc.date.accessioned | 2020-08-12T07:23:29Z | |
dc.date.available | 2020-08-12T07:23:29Z | |
dc.date.issued | 2019-03-28 | |
dc.identifier.issn | 2041-6520 | en_US |
dc.identifier.uri | http://hdl.handle.net/10679/6761 | |
dc.identifier.uri | https://pubs.rsc.org/en/content/articlelanding/2019/sc/c8sc04044c#!divAbstract | |
dc.description.abstract | Recent demonstrations of melting in the metal-organic framework (MOF) family have created interest in the interfacial domain between inorganic glasses and amorphous organic polymers. The chemical and physical behaviour of porous hybrid liquids and glasses is of particular interest, though opportunities are limited by the inaccessible melting temperatures of many MOFs. Here, we show that the processing technique of flux melting, borrowed' from the inorganic domain, may be applied in order to melt ZIF-8, a material which does not possess an accessible liquid state in the pure form. Effectively, we employ the high-temperature liquid state of one MOF as a solvent for a secondary, non-melting MOF component. Differential scanning calorimetry, small- and wide-angle X-ray scattering, electron microscopy and X-ray total scattering techniques are used to show the flux melting of the crystalline component within the liquid. Gas adsorption and positron annihilation lifetime spectroscopy measurements show that this results in enhanced, accessible porosity to a range of guest molecules in the resultant flux melted MOF glass. | en_US |
dc.description.sponsorship | Royal Society of London ; Engineering & Physical Sciences Research Council (EPSRC) ; National Science Foundation (NSF) ; EU Horizon 2020 programme under the SINE2020 project ; European Research Council under the European Union's Seventh Framework Program/ERC Grant ; National Science Foundation (NSF) NSF - Directorate for Mathematical & Physical Sciences (MPS) ; Australian Research Council ; Veski Inspiring Women Fellowship ; Henslow Research Fellowship | |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/2007-2013 | |
dc.relation.ispartof | Chemical Science | |
dc.rights | openAccess | |
dc.title | Flux melting of metal–organic frameworks | en_US |
dc.type | Article | en_US |
dc.description.version | Publisher version | en_US |
dc.peerreviewed | yes | en_US |
dc.publicationstatus | Published | en_US |
dc.contributor.department | Özyeğin University | |
dc.contributor.authorID | (ORCID 0000-0002-6059-6067 & YÖK ID 260094) Eruçar, İlknur | |
dc.contributor.ozuauthor | Fındıkçı, İlknur Eruçar | |
dc.identifier.volume | 10 | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.startpage | 3592 | en_US |
dc.identifier.endpage | 3601 | en_US |
dc.identifier.wos | WOS:000463759100014 | |
dc.identifier.doi | 10.1039/c8sc04044c | en_US |
dc.identifier.scopus | SCOPUS:2-s2.0-85063325873 | |
dc.contributor.authorFemale | 1 | |
dc.relation.publicationcategory | Article - International Refereed Journal - Institution Academic Staff |
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